Here are the spacing commands for LaTeX in math mode.
\quad - a space equal to the current font size (horizontally)
\qquad - is a double \quad
\, or \thinspace - small space, 3/18 of a quad
\: or \medspace - medium space, 4/18 of a quad
\; or \thickspace- large space, 5/18 of a quad
\! - negative small space, -3/18 of a quad
\negmedspace - negative medium space, -4/18 of a quad
\negthickspace - negative large space, -5/18 of a quad
The \medspace, \thickspace, \negmedspace, and \negthickspace commands require the amsmath package.
Found the full forms here: Special LaTeX Characters - 6. Math spacing commands - http://www.combinatorics.net/weblib/A.9-10/a9.html
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