**\quad**- a space equal to the current font size (horizontally)

**\qquad**- is a double \quad

**\,**or

**\thinspace**- small space, 3/18 of a quad

**\:**or

**\medspace**- medium space, 4/18 of a quad

**\;**or

**\thickspace**- large space, 5/18 of a quad

**\!**- negative small space, -3/18 of a quad

**\negmedspace**- negative medium space, -4/18 of a quad

**\negthickspace**- negative large space, -5/18 of a quad

The \medspace, \thickspace, \negmedspace, and \negthickspace commands require the amsmath package.

Found the full forms here: Special LaTeX Characters - 6. Math spacing commands - http://www.combinatorics.net/weblib/A.9-10/a9.html

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